Kugurisha Bishyushye kandi Byiza Cesium Carbonate CAS 534-17-8 hamwe nigiciro cyiza

Ibintu byinshi biranga karubone ya cesium muri synthesis organique ikomoka kuri acide yoroshye ya Lewis ya cesium ion, ituma ishonga mumashanyarazi nka alcool, DMF na ether.Gukemura neza mumashanyarazi kama ituma karubone ya cesium igira uruhare mubisubizo byimiti iterwa na palladium reagent nkibishingwe bidafite ingufu, nka Heck, Suzuki na Sonogashira.Kurugero, Suzuki cross reaction hamwe na cesium karubone yashoboye kubona umusaruro wa 86%, mugihe reaction imwe na sodium karubone cyangwa triethylamine yari 29% na 50% gusa.Mu buryo nk'ubwo, muri Heck reaction ya methacrylate na chlorobenzene, karubone ya cesium ugereranije nibindi bishingwe, nka potasiyumu karubone, sodium acetate, triethylamine, fosifate ya potasiyumu, yerekanye ibyiza bigaragara.Cesium carbone nayo ifite akamaro gakomeye muri o-alkylation yibintu bya fenol.Biravugwa ko reaction ya fenol O-alkylation muri cesium karubone idafite amazi yo mu mazi ishobora guhura na anion ya phenoxyethylene, bityo reaction ya alkylation nayo ishobora kubaho kuri halogene ya kabiri hamwe nibikorwa byinshi kandi byoroshye kurandura.Cesium carbone nayo ifite akamaro gakomeye muguhuza ibicuruzwa bisanzwe.Kurugero, muri synthesis ya Lipogrammistin-ikomatanyirizo muntambwe yingenzi ifunze-loop reaction, cesium karubone nkibishingwe kama organique irashobora gukoreshwa kugirango ibone ibicuruzwa bifunze-bifite umusaruro mwinshi.Byongeye kandi, karubone ya cesium ifite akamaro gakomeye mugukomera gukomeye kama bitewe nubushobozi bwayo bwiza mumashanyarazi.Carboxylate cyangwa karbamate irashobora guhurizwa hamwe kumusaruro mwinshi mugutera ibice bitatu bya aniline hamwe na halogene ikomeye ishyigikiwe nikirere cya dioxyde de carbone.Munsi ya microwave irrasiyo, karubone ya cesium irashobora kandi gukoreshwa nkibanze kugirango hamenyekane esterification reaction hagati ya acide benzoic na halogene ikomeye.